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New Sesquiterpene Glycosides from Culture Hairy Roots of Catharanthus roseus
作者姓名:CHUNG  ILL-Min ALl  Mohd CHUN  Se-Chul LEE  Sun-Joo SAN  Ka-Yiu CHRISTIE  A. M. Peebles AHMAD  Ateeque
作者单位:[1]Department of Applied Life Science, Konkuk University, Seoul 143-701, South Korea [2]Faculty of Pharmacy, Hamdard University, New Delhi 110062, India [3]Department of Bioengineering, Rice University, Houston, Texas 77005, USA
摘    要:Two new compounds cadin-2-en-1β-ol-1β-D-glucuronopyranoside (1), guaia-l,7-dien-3β,13-diol-13α-D- glucofuranoside (2) along with three known compounds have been isolated from the culture hairy roots of Catharanthus roseus. Their structures have been elucidated with the help of 500 MHz NMR using 1D and 2D spectral methods: viz: ^1H and ^13C NMR, ^1H-^1H COSY, ^1H-^13C HETCOR and DEPT aided by ELMS, FAB-MS, HR-FABMS and IR spectroscopy.

关 键 词:类倍半萜烯  糖苷  培养基  化学分析
修稿时间:2007-03-19

New Sesquiterpene Glycosides from Culture Hairy Roots of Catharanthus roseus
CHUNG, ILL-Min ALl, Mohd CHUN, Se-Chul LEE, Sun-Joo SAN, Ka-Yiu CHRISTIE, A. M. Peebles AHMAD, Ateeque.New Sesquiterpene Glycosides from Culture Hairy Roots of Catharanthus roseus[J].Chinese Journal of Chemistry,2007,25(11):1695-1699.
Authors:ILL-Min CHUNG  Mohd ALI  Se-Chul CHUN  Sun-Joo LEE  Ka-Yiu SAN  A M Peebles CHRISTIE  Ateeque AHMAD
Institution:1. Department of Applied Life Science, Konkuk University, Seoul 143-701, South Korea;2. Faculty of Pharmacy, Hamdard University, New Delhi 110062, India;3. Department of Bioengineering, Rice University, Houston, Texas 77005, USA;4. Tel.: 82-2-450-3730;5. Fax: 82-2-446-7856
Abstract:Two new compounds cadin-2-en-1β-ol-1β-D-glucuronopyranoside ( 1 ), guaia-1,7-dien-3β,13-diol-13α-D- glucofuranoside ( 2 ) along with three known compounds have been isolated from the culture hairy roots of Catharanthus roseus. Their structures have been elucidated with the help of 500 MHz NMR using 1D and 2D spectral methods: viz: 1H and 13C NMR, 1H-1H COSY, 1H-13C HETCOR and DEPT aided by EIMS, FAB-MS, HR-FABMS and IR spectroscopy.
Keywords:Catharanthus roseus  Apocynaceae  culture hairy root  new constituent
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