| Synthesis and Characterization of New Macrocyclic Cu（Ⅱ） Complexes from Various Diamines, Copper（Ⅱ） Nitrate and 1,4-Bis（2-formylphenoxy）butane |
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| 作者姓名： | ILHAN Salih TEMEL Hamdi KILIC Ahmet |
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| 作者单位： | [1]Chemistry Department, Faculty of Education, Dicle University, Diyarbakir 21010, Turkey [2]Chemistry Department, Faculty of Art and Science, Harran University, Sanhurfa 63100, Turkey |
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| 基金项目： | Project supported by TUBITAK Research Fund 106T475 （No. TBAG-HD/208） and Research Fund of Harran University （Sanliurfa, Turkey）. |
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| 摘 要： | Six new macrocyclic complexes were synthesized by a template reaction of 1,4-bis（2-formylphenoxy）butane with diamines and Cu（NO3）2·3H2O and their structures were proposed on the basis of elemental analysis, FT-IR, UV-Vis, magnetic susceptibility measurements, molar conductivity measurements and mass spectra. The metal to ligand molar ratios of the Cu（Ⅱ） complexes were found to be 1 ： 1. The Cu（Ⅱ） complexes are 1 ： 2 electrolytes as shown by their molar conductivities （∧m） in DMF at 10^-3 mol·L^-1. Due to the existence of free ions the Cu（Ⅱ） complexes are electrically conductive. Their configurations were proposed to be probably distorted octahedral.
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| 关 键 词： | 二胺 硝酸铜 铜复合物 合成 特征 |
| 修稿时间： | 2007-04-10 |
Synthesis and Characterization of New Macrocyclic Cu(II) Complexes from Various Diamines,Copper(II) Nitrate and 1,4‐Bis(2‐formylphenoxy)butane |
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| ILHAN, Salih TEMEL, Hamdi KILIC, Ahmet.Synthesis and Characterization of New Macrocyclic Cu(II) Complexes from Various Diamines,Copper(II) Nitrate and 1,4‐Bis(2‐formylphenoxy)butane[J].Chinese Journal of Chemistry,2007,25(10):1547-1550. |
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| Authors: | ILHAN Salih TEMEL Hamdi KILIC Ahmet |
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| Institution: | a Chemistry Department, Faculty of Education, Dicle University, Diyarbakir 21010, Turkey; b Chemistry Department, Faculty of Art and Science, Harran University, Sanhurfa 63100, Turkey |
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| Abstract: | Six new macrocyclic complexes were synthesized by a template reaction of 1,4‐bis(2‐formylphenoxy)butane with diamines and Cu(NO3)2·3H2O and their structures were proposed on the basis of elemental analysis, FT‐IR, UV‐Vis, magnetic susceptibility measurements, molar conductivity measurements and mass spectra. The metal to ligand molar ratios of the Cu(II) complexes were found to be 1:1. The Cu(II) complexes are 1:2 electrolytes as shown by their molar conductivities (Λm) in DMF at 10?3 mol·L?1. Due to the existence of free ions the Cu(II) complexes are electrically conductive. Their configurations were proposed to be probably distorted octahedral. |
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| Keywords: | macrocyclic Schiff base complex 1 4‐bis(2‐formylphenoxy)butane diamine copper(II) complex |
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