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Novel Properties of Photochromic Spirooxazine Nanoparticles
作者姓名:刘媛媛  樊美公  张长瑞  盛小海  姚建年
作者单位:[1]Beijing National Laboratory of Molecular Sciences (BNLMS), and Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China [2]Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100039, China [3]Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, China
基金项目:Project supported by the National Natural Science Foundation of China (Nos. 50221201, 90301010, 50502033, 20302088), the Chinese Academy of Sciences and the National Research Fund for Fundamental Key Projects No. 973 (No. 2006CB806200).
摘    要:The nanoparticles of a spirooxazine (SPO) and its photomerocyanine (PMC) were prepared through the reprecipitation method. Two distinct features were observed. One is that the decaying lifetime for PMC nanoparticles was 600 times of that for the dispersed molecules, and the other is that the fluorescence intensity of SPO nanoparticles was enhanced by 240 times of that of the dispersed monomer.

关 键 词:光致变色性  纳米颗粒  衰退时间  荧光
修稿时间:2006-11-16

Novel Properties of Photochromic Spirooxazine Nanoparticles
LIU, Yuan-Yuan FAN, Mei-Gong ZHANG, Chang-Rui SHENG, Xiao-Hai YAO, Jian-Nian, and Key Laboratory of Photochemistry.Novel Properties of Photochromic Spirooxazine Nanoparticles[J].Chinese Journal of Chemistry,2007,25(11):1612-1616.
Authors:LIU  Yuan-Yuan FAN  Mei-Gong ZHANG  Chang-Rui SHENG  Xiao-Hai YAO  Jian-Nian  and Key Laboratory of Photochemistry
Institution:1Beijing National Laboratory of Molecular Sciences (BNLMS
Abstract:The nanoparticles of a spirooxazine (SPO) and its photomerocyanine (PMC) were prepared through the reprecipitation method. Two distinct features were observed. One is that the decaying lifetime for PMC nanoparticles was 600 times of that for the dispersed molecules, and the other is that the fluorescence intensity of SPO nanoparticles was enhanced by 240 times of that of the dispersed monomer.
Keywords:nanoparticle  photochromism  decay lifetime  fluorescence
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