| ReCl（CO）5-catalyzed Reactions of Aromatic Compounds with 1,3,5-Trioxane or Aqueous Formaldehyde Affording Diarylmethanes |
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| 引用本文： | 华瑞茂 何俊义 孙宏滨. ReCl（CO）5-catalyzed Reactions of Aromatic Compounds with 1,3,5-Trioxane or Aqueous Formaldehyde Affording Diarylmethanes[J]. 中国化学, 2007, 25(1): 132-135. DOI: 10.1002/cjoc.200790009 |
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| 作者姓名： | 华瑞茂 何俊义 孙宏滨 |
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| 作者单位： | Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics ＆ Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20573061）. |
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| 摘 要： | ReCI（CO）5 catalyzed the dehydration reaction of aromatic compounds with 1,3,5-trioxane or aqueous formaldehyde （37 wt%） under air. The reactions of a variety of aromatic compounds beating electron-donating group（s） with 1,3,5-trioxane afforded the corresponding diarylmethanes in moderate to good yields.
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| 关 键 词： | 芳族化合物 脱水反应 铼配合物 催化剂 1 3 5-三环氧乙烷 福尔马林 二芳基甲烷 |
| 修稿时间： | 2006-02-282006-09-12 |
ReCl(CO)5‐catalyzed Reactions of Aromatic Compounds with 1,3,5‐Trioxane or Aqueous Formaldehyde Affording Diarylmethanes |
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| HUA, Rui-Mao, HE, Jun-Yi, SUN, Hong-Bin. ReCl(CO)5‐catalyzed Reactions of Aromatic Compounds with 1,3,5‐Trioxane or Aqueous Formaldehyde Affording Diarylmethanes[J]. Chinese Journal of Chemistry, 2007, 25(1): 132-135. DOI: 10.1002/cjoc.200790009 |
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| Authors: | HUA Rui-Mao HE Jun-Yi SUN Hong-Bin |
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| Affiliation: | Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China |
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| Abstract: | ReCl(CO)5 catalyzed the dehydration reaction of aromatic compounds with 1,3,5‐trioxane or aqueous formaldehyde (37 wt%) under air. The reactions of a variety of aromatic compounds bearing electron‐donating group(s) with 1,3,5‐trioxane afforded the corresponding diarylmethanes in moderate to good yields. |
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| Keywords: | aromatic catalysis dehydration diarylmethane trioxane |
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