Abstract: | ![]() Crystal Structure Determinations of Bis(pentafluorophenyl)tellurium Dihalides (C6F5)2TeHal2 (Hal = Cl, Br) Bis(pentafluorophenyl)telluriumdichloride and bis(pentafluorophenyl)telluriumdibromide crystallize at 10°C or 20°C from CH2Cl2 or CHCl3 solution in the monoclinic space group P21/c with a = 649.5(1) pm, b = 1 275.6(2) pm, c = 1 816.2(5) pm, β = 92.89(2)° for (C6F5)2TeCl2 and a = 694.4(1) pm, b = 1 579.1(2) pm, c = 1 423.4(1) pm, β = 90.22(2)° for (C6F5)2TeBr2 with four formula units per each unit cell. |