Redox-active dinuclear macrocycles designed to bind and activate small molecules |
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| Affiliation: | Department of Chemistry, University of Birmingham, P.O. Box 363, Birmingham, B15 2TT U.K.;B.P. Research Centre, Sunbury-on-Thames, Middlesex, TW16 7LN U.K.;A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova Str., Moscow 119991, Russian Federation |
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| Abstract: | ![]()
The syntheses, electrochemistry and preliminary coordination studies of novel redox-active dinucleating macrocyclic molecules (FcCH2SCH2RCH2SCH2)2 (Fc = ferrocenyl, R = CH2SCH2, NC5H3) and their acyclic analogues, which incorporate ferrocene subunits into cyclic and acyclic structural frameworks are described. |
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