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基于六硼化镧与壳聚糖的光热转换生物材料
引用本文:李奕杉,钟年丙,廖强,付乾,黄云,夏奡,朱恂.基于六硼化镧与壳聚糖的光热转换生物材料[J].发光学报,2017,38(8).
作者姓名:李奕杉  钟年丙  廖强  付乾  黄云  夏奡  朱恂
作者单位:1. 重庆大学 低品位能源利用技术及系统教育部重点实验室,重庆 400044;重庆大学动力工程学院 工程热物理研究所,重庆 400044;2. 重庆理工大学 光纤传感与光电检测重庆市重点实验室 重庆市现代光电检测技术与仪器重点实验室,重庆,400054
基金项目:国家自然科学基金委国际(地区)合作与交流项目,国家自然科学基金,重庆市博士后科研项目,中央高校基本科研业务费(106112015CDJXY140003)资助项目 Supported by International Cooperation and Exchanges NSFC,National Natural Science Foundation of China,Postdoctoral Research Project in Chongqing,Fundamental Research Funds for The Central Universities
摘    要:为实现光合细菌(PSB)产氢过程的光分频利用,用六硼化镧(LaB_6)和壳聚糖制备了光热转换发光发热生物材料,研究了不同LaB_6纳米颗粒的生物材料在可见光下的吸光特性和光热转换特性。研究发现:该生物材料能较好地透过510~650 nm波长的光为PSB产氢供给光能,而其他波段的光用于激发LaB_6粒子产热为PSB提供热能。LaB_6纳米颗粒的吸光度及光热转换能力受颗粒尺寸影响显著,当生物材料中LaB_6颗粒平均水力直径为295 nm时,12 min内的温升速率为0.41℃/min,是载玻片的5.4倍。

关 键 词:光合细菌  生物材料  六硼化镧  光热转换

Photo-thermal Biomaterial Based on Lanthanum Hexaboride (LaB6) and Chitosan
LI Yi-shan,ZHONG Nian-bing,LIAO Qiang,FU Qian,HUANG Yun,XIA Ao,ZHU Xun.Photo-thermal Biomaterial Based on Lanthanum Hexaboride (LaB6) and Chitosan[J].Chinese Journal of Luminescence,2017,38(8).
Authors:LI Yi-shan  ZHONG Nian-bing  LIAO Qiang  FU Qian  HUANG Yun  XIA Ao  ZHU Xun
Abstract:To realize spectral beam splitting technology in the bioprocess of hydrogen production by photosynthetic bacteria (PSB), a luminous exothermic biomaterial based on lanthanum hexaboride (LaB6) and chitosan was fabricated.The absorption spectra and photothermal properties of biomaterial with different LaB6 particles were investigated in the visible spectrum.The results show that the biomaterial can transmit the light in the spectrum of 510-650 nm for PSB, and other light energy will convert to heat energy for PSB.In addition, the absorption and photothermal performance of LaB6 particles are significantly effected by the particle size.When the average hydraulic diameter of LaB6 particles in the biomaterial is 296 nm, the rate of temperature rise is 0.41 ℃/min over 12 min, which is 5.4 times of glass slide.
Keywords:photosynthetic bacteria  biomaterial  LaB6  photothermal conversion
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