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Magnetism at spinel thin film interfaces probed through soft X-ray spectroscopy techniques |
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| Authors: | R.V. Chopdekar M. Liberati L.F. Kourkoutis B.B. Nelson-Cheeseman A. Doran D.A. Muller |
| Affiliation: | a School of Applied and Engineering Physics, Cornell University, Ithaca, NY 14853, USA b Department of Materials Science and Engineering, University of California, Berkeley, CA 94720, USA c Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA d Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616, USA |
| Abstract: | Magnetic order and coupling at the interfaces of highly spin polarized Fe3O4 heterostructures have been determined by surface sensitive and element specific soft X-ray spectroscopy and spectro-microscopy techniques. At ambient temperature, the interface between paramagnetic CoCr2O4 or MnCr2O4 and ferrimagnetic Fe3O4 isostructural bilayers exhibits long range magnetic order of Co, Mn and Cr cations which cannot be explained in terms of the formation of interfacial MnFe2O4 or CoFe2O4. Instead, the ferrimagnetism is induced by the adjacent Fe3O4 layer and is the result of the stabilization of a spinel phase not achievable in bulk form. Magnetism at the interface region is observable up to 500 K, far beyond the chromite bulk Curie temperature of 50-95 K. |
| Keywords: | Spinel thin films X-ray absorption spectroscopy X-ray magnetic circular dichroism Proximity-induced magnetism |
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