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| Formation and Structure of [Al_(13)(μ_3-OH)_6(μ_2-OH)_6(μ_2-OH)_(12)(H_2O)_(24)]Cl_(15)·13H_2O | |
| 作者姓名： | SUN Zhonga② ZHAO Hai-Dongb TONG Hong-Ge-Era WANG Rui-Fena ZHU Fan-Zhuc a (College of Chemistry and Chemical Engineering Inner Mongolia University Hohhot 010021 China) b (Chemistry Department Yanbei Normal College Datong 037009 China) c (Survey and Design Institute of Water Resources and Hydropower Inner Mongolia Autonomous Region Hohhot 010020 China) |
| 作者单位： | SUN Zhonga② ZHAO Hai-Dongb TONG Hong-Ge-Era WANG Rui-Fena ZHU Fan-Zhuc a (College of Chemistry and Chemical Engineering，Inner Mongolia University，Hohhot 010021，China) b (Chemistry Department，Yanbei Normal College，Datong 037009，China) c (Survey and Design Institute of Water Resources and Hydropower，Inner Mongolia Autonomous Region，Hohhot 010020，China) |
| 基金项目： | Project supported by NNSFC (No. 20563002), NSF of Inner Mongolia Autonomous Region (200508010204) and Key Item Foundation of Education Committee of Inner Mongolia Autonomous Region (ZD01070) |
| 摘 要： | 1 INTRODUCTION At present, the polyaluminium compounds are mainly studied by single-crystal X-ray diffraction method to obtain the components, structures and exis- tence forms of aluminium in hydrolysis system, and then hydrolysis courses and mechanisms of each hydrolytic polyaluminium cation could be further dis- closed[1～5]. Generally, the single crystals suitable for X-ray diffraction are obtained from the crystallization of polyaluminium cations into sulfates or selenates. Following … |
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