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Mechanistic study of the addition reaction of TeCl4 to alkynes: Participation of TeCl3 centered-radical |
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| Authors: | Artur F Keppler Giselle Cerchiaro João V Comasseto |
| Institution: | a Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, 05508-900 São Paulo, SP, Brazil b Centro de Ciências Naturais e Humanas, Universidade Federal do ABC, Santo André, SP, Brazil |
| Abstract: | The mechanism of the addition reaction of TeCl4 to alkynes was indirectly established by the detection of TeCl3 centered radicals using EPR spin trapping, ESI-MS and ESI-MS/MS characterization. |
| Keywords: | Tellurium Radicals DBNBS EPR Reaction mechanism |
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