Solvent Effects on the piezochromism of molybdenum(IV) and tungsten(IV) anions [M(CN)3O(diimine)]− |
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| Authors: | Nowicka Beata Burgess John Parsons Simon A Samotus Alina Szklarzewicz Janusz |
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| Institution: | (1) Department of Chemistry, University of Leicester, Leicester, LE1 7RH, UK;(2) Faculty of Chemistry, Jagiellonian University, 30-060 Kraków, Poland |
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| Abstract: | Solvatochromism of the Mo(CN)3O(phen)]− ion has been studied. Solvent effects on pressure dependence (up to 1.25 kbar) of wavelengths of maximum absorption for charge-transfer
bands of several molybdenum(IV) and tungsten(IV) complexes, M(CN)3O(diimine)]− (M = Mo or W), are described. The effects of applied pressure are larger for less polar unstructured solvents than for highly
polar hydrogen-bonded solvents.
This revised version was published online in June 2006 with corrections to the Cover Date. |
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