Synthesis and crystal structure of [V_2(μ-S_2)_2(S_2CNEt_2)_4]·2CH_3Cl

V_2(μ-S_2)_2(S_2CNEt_2)_4].2CH_3Cl was synthesized by the reaction of NaS_2CNEt_2,Li_2S andVOCl_3 at room temperature.Crystal data:M=1061.3,space group Pbca,with the orthorhombicparameters:a=20.123(3),b=20.485(4),c=10.911(3),V=4497.7,Z=4,D_c=1.57g/cm~3,Mo Kσradiation(λ=0.71069()?),μ=13.2 cm~(-1),F(000)=2168.Final R=0.041 and R_w=0.047 for 2288 ob-served reflections with I>3σ(1).The coordination sphere of each V atom in title compound is a dis-torted tetragonal prism composed of two bidentate dithiocarbamate and two S_(2~((2-)) ligands.The V—Vdistance is 2.890 while the V—S distances fall in the range of 2.422—2.505.

Synthesis and crystal structure of [V2(μ-S2)2(S2CNEt2)4] · 2CH3Cl

V₂(μ-S₂)₂(S₂CNEt₂)₄] 2CH₃Cl was synthesized by the reaction of NaS₂CNEt₂, Li₂S and VOCl₃ at room temperature. Crystal data: M= 1061.3, space group Pbca, with the orthorhombic parameters: a=20.123(3), b = 20.485(4)₁ c=10.911(3)A, V=4497.7ų, Z=4, D_c=1.57 g/cm³, Mo K_o radiation (λ=0.71069 Å), μ = 13.2 cm^?1, F(000)—2168. Final R = 0.041 and R_w=0.047 for 2288 observed reflections with I>3σ(I). The coordination sphere of each V atom in title compound is a distorted tetragonal prism composed of two bidentate dithiocarbamate and two S₂^1? ligands. The V—V distance is 2.890 Å while the V—S distances fall in the range of 2.422–2.505 Å.