二个钴5-磺酸基水杨酸、邻菲罗啉配合物的合成、次级合成与结构

Cobait（Ⅱ） nitrate reacted with 1,10-phenanthroline （phen） and 5-sulfosaiicylic acid （H3ssal） to yield the cobait（Ⅰ） complex Co（phen）2（H2O）2]（Hssal）o4H2O （1） and the reaction of 1 with copper acetate led to a novel complex Co（phen）（H2O）4]Cu2（ssal）2（phen）2]·5H2O （2）. These two complexes were cationanion species and the cationic motif Co（phen）2（H2O）2]^2＋of 1 could be converted to Co（phen）（H2O）4]^2＋ in the formation process of new anion Cu2（phen）2（ssal）2]^2- of 2. In both complexes abundant hydrogen bonds construct different supramolecular architectures, thus the conversion reaction can provide a new path to create novel supramolecular network.

Secondary Synthesis of Two Cobalt Complexes by the Use of 5-Sulfosalicylate and 1 ,lO-Phenanthroline and Their Crystal Structures

Cobalt(II) nitrate reacted with 1,10‐phenanthroline (phen) and 5‐sulfosalicylic acid (H₃ssal) to yield the cobalt(II) complex Co(phen)₂(H₂O)₂](Hssal)·4H₂O ( 1 ) and the reaction of 1 with copper acetate led to a novel complex Co(phen)(H₂O)₄]Cu₂(ssal)₂(phen)₂]·5H₂O ( 2 ). These two complexes were cation‐anion species and the cationic motif Co(phen)₂(H₂O)₂]²⁺of 1 could be converted to Co(phen)(H₂O)₄]²⁺ in the formation process of new anion Cu₂(phen)₂(ssal)₂]^2? of 2 . In both complexes abundant hydrogen bonds construct different supramolecular architectures, thus the conversion reaction can provide a new path to create novel supramolecular network.