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预处理对垃圾焚烧飞灰玻璃化的影响
引用本文:陈德珍,贾其亮,袁园,张鹤声.预处理对垃圾焚烧飞灰玻璃化的影响[J].工程热物理学报,2005,26(3):523-526.
作者姓名:陈德珍  贾其亮  袁园  张鹤声
作者单位:同济大学热能与环境工程研究所,上海,200092;同济大学污染控制与资源化研究国家重点实验室,上海,200092
基金项目:上海市青年科技启明星计划;中国-丹麦合作项目
摘    要:在垃圾焚烧飞灰进行熔融玻璃化之前,先用磷酸盐或绿矾溶液对飞灰进行洗涤,研究这种化学稳定化预处理对飞灰玻璃固化效果的影响。结果表明当使用磷酸盐溶液或磷酸盐与绿矾(FeSO4·7H2O)溶液一起对飞灰进行预处理、并且磷酸盐用量达2g磷/kg干灰时,对飞灰的熔融玻璃化有良好的促进效果,经过预处理后的飞灰通过玻璃化过程可实现对所检测的Pb、Hg、As、Cd、Cr五种重金属的全部稳定化,并且在熔融过程中烟尘的产生和重金属的挥发得到有效抑制。

关 键 词:预处理  焚烧飞灰  玻璃化  磷酸盐  绿矾
文章编号:0253-231X(2005)03-0523-04
修稿时间:2004年12月24

INFLUENCE OF PRETREATMENT ON VITRIFICATION OF INCINERATOR FLY ASH
CHEN De-zhen,JIA Qi-Liang,YUAN Yuan,ZHANG He-sheng.INFLUENCE OF PRETREATMENT ON VITRIFICATION OF INCINERATOR FLY ASH[J].Journal of Engineering Thermophysics,2005,26(3):523-526.
Authors:CHEN De-zhen  JIA Qi-Liang  YUAN Yuan  ZHANG He-sheng
Abstract:In order to test the influence of chemical pretreatment on the vitrification of municipal solid waste incineration fly ash, phosphate solution and copperas solution were used to wash the fly ashes before they were undergone vitrification process. Experimental results showed that when phosphate solution or both phosphate and copperas solutions were used with the consumption of phosphate reaching 2 g phosphorus per kilogram fly ash, good promotion effect on the vitrification process had been obtained; and after those pretreatments the vitrification was characterized with satisfied stabilized effect for the five tested heavy metals, namely Pb, Hg, As, Cd and Cr, and with less production of dust and lower volatilization of heavy metals in the melting process.
Keywords:chemical pretreatment  incineration fly ash  vitrification  phosphate  copperas
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