| 正丁胺对苯膦酸铜的插层反应研究 |
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| 引用本文： | 魏颖,张向东,关宏宇,葛春华,张鹏,乔玉.正丁胺对苯膦酸铜的插层反应研究[J].分子科学学报,2007,23(4):266-270. |
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| 作者姓名： | 魏颖 张向东 关宏宇 葛春华 张鹏 乔玉 |
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| 作者单位： | 1. 辽宁大学化学学院,辽宁,沈阳,110036;渤海大学化学化工学院,辽宁,锦州,121013
2. 辽宁大学化学学院,辽宁,沈阳,110036 |
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| 基金项目： | 辽宁省科技厅基金资助项目(200371028)，沈阳市科技局基金资助项目(1022037) |
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| 摘 要： | 分别采用溶液搅拌和超声的方法,研究了有机正丁胺分子对苯膦酸铜的插层反应.对插层复合物进行了红外光谱(IR)、X射线粉末衍射(XRD)和热重分析等测试及结构分析.结果表明,有机正丁胺的插入使得苯膦酸铜的层间距增大.
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| 关 键 词： | 苯磷酸铜 合成 插层 超声 |
| 文章编号： | 1000-9035（2007）04-0266-05 |
| 修稿时间： | 2007-02-01 |
The study of the intercalation reaction of N-butylamine with copper phenylphosphonate |
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| WEI Ying,ZHANG Xiang-dong,GUAN Hong-yu,GE Chun-hua,ZHANG Peng,QIAO Yu.The study of the intercalation reaction of N-butylamine with copper phenylphosphonate[J].Journal of Molecular Science,2007,23(4):266-270. |
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| Authors: | WEI Ying ZHANG Xiang-dong GUAN Hong-yu GE Chun-hua ZHANG Peng QIAO Yu |
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| Institution: | 1. College of Chemistry, Liaoning University, Shengyang 110036, China; 2. College of Chemistry and Engineering,Bohai University,Jinzhou 121013,China |
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| Abstract: | The intercalation reaction of n-butylamin into copper phenylphosphonate was reported by stirring and ultrasonic method.The intercalation compounds are characterized by the XRD,elemental analysis,TG and IR spectra.The interlayer distance of intercalation compounds is larger than that of copper phenylphosphonate.The difference between the two complexes made by two methods is also discussed with the experimental results. |
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| Keywords: | copper phenylphosphonate synthesize intercalation ultrasonic |
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