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Gear-like array of (H_2O)_(12) as building blocks in one-dimensional supramolecular assembly
引用本文:Chun Hua Ge Xiang Dong Zhang Yong Chao Ma Lei Guan Chun Yue Shi Xiao Yan Zhang Ya Nan Guo Qi Tao Liu College of Chemistry,Liaoning University,Shenyang 110036,China. Gear-like array of (H_2O)_(12) as building blocks in one-dimensional supramolecular assembly[J]. 中国化学快报, 2007, 0(11)
作者姓名:Chun Hua Ge Xiang Dong Zhang Yong Chao Ma Lei Guan Chun Yue Shi Xiao Yan Zhang Ya Nan Guo Qi Tao Liu College of Chemistry  Liaoning University  Shenyang 110036  China
作者单位:Chun Hua Ge Xiang Dong Zhang Yong Chao Ma Lei Guan Chun Yue Shi Xiao Yan Zhang Ya Nan Guo Qi Tao Liu College of Chemistry,Liaoning University,Shenyang 110036,China
摘    要:The preparation and crystal structure of complex Co(Hsae)_2·2H_2O (1,H_2sae=N-salicylidene-2-iminoethanol) are reported.X- ray analysis revealed that every six Co(Hsae)_2 forms a cyclic chip and every 12 water forms a novel gear-like cluster.Acting as building blocks,the gear-like water cluster and complex chip are connected in A-B fashion and extend into one-dimensional supramolecular chain.Hydrogen bond is the primary bridging force in the formation of supramolecular framework.

关 键 词:Co(Ⅱ)complex  N-Salicylidene-2-iminoethanol  Hydrogen bond  Water cluster  One-dimensional chain  Supramolecular chemistry

Gear-like array of (H_2O)_(12) as building blocks in one-dimensional supramolecular assembly
Chun Hua Ge Xiang Dong Zhang Yong Chao Ma Lei Guan Chun Yue Shi Xiao Yan Zhang Ya Nan Guo Qi Tao Liu College of Chemistry,Liaoning University,Shenyang ,China. Gear-like array of (H_2O)_(12) as building blocks in one-dimensional supramolecular assembly[J]. Chinese Chemical Letters, 2007, 0(11)
Authors:Chun Hua Ge Xiang Dong Zhang Yong Chao Ma Lei Guan Chun Yue Shi Xiao Yan Zhang Ya Nan Guo Qi Tao Liu College of Chemistry  Liaoning University  Shenyang   China
Affiliation:Chun Hua Ge Xiang Dong Zhang Yong Chao Ma Lei Guan Chun Yue Shi Xiao Yan Zhang Ya Nan Guo Qi Tao Liu College of Chemistry,Liaoning University,Shenyang 110036,China
Abstract:
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