Tartradiamide formation by thermolysis of tartaric acid with alkylamines |
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| Authors: | Susana V. Gonzalez Per Carlsen |
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| Affiliation: | aDepartment of Chemistry, Norwegian University of Science and Technology, N-7491 Trondheim, Norway |
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| Abstract: | The formation of N,N′-dialkyltartramides by microwave-assisted reactions and by conventional thermolysis was investigated. Thus, the thermolysis of l-tartaric acid with n-hexylamine at 200 °C showed that all the possible stereoisomers of N,N′-dihexyltartramide were formed albeit with partial racemization only. The same was observed for the microwave-assisted reaction. |
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| Keywords: | Thermolysis Diastereoselective Amphiphiles Tartradiamide |
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