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Hyperfine structure in EPR spectra of the catalytic system TiCl4 + Al(i-C4H9)3
Authors:N. Makhiyanov  V. V. Biktagirov
Affiliation:(1) Nizhnekamskneftekhim OAO, 47 prosp. Stroitelei, Nizhnekamsk, 423574, Republic of Tatarstan, Russia;(2) Nizhnekamsk Chemical Engineering Institute, Russia
Abstract:In an EPR study of the catalytic system TiCl4 + Al(i-C4H9)3 in toluene and isopentane in TiCl4/oligopiperylene + Al(i-C4H9)3 in toluene, we have observed a dependence of the linewidth of the hyperfine structure on the mobility of the complex in solution. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 2, pp. 174–177, March–April, 2007.
Keywords:catalytic system TiCl4 + Al(i-C4H9)3   electron paramagnetic resonance  hyperfine structure
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