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Raman spectroscopy of arsenolite: crystalline cubic As4O6
Authors:Sean J Gilliam  Scott J Kirkby  Daniel Zeroka
Institution:
  • a Department of Chemistry, University of Missouri-Rolla, Rolla, MO 65409, USA
  • b US Army Edgewood Chemical and Biological Center, Aberdeen Proving Ground, Aberdeen, MD 21010, USA
  • c Department of Chemistry, Lehigh University, Bethlehem, PA 18015, USA
  • Abstract:The complete Raman spectrum of arsenolite, cubic crystalline As4O6, is reported for the first time. The previously unseen Eg mode has been found at 443 cm−1. Further, there is additional support for the assignment of the 415 cm−1 mode as T2g.
    Keywords:Raman  Arsenolite  As2O3  As4O6  Claudetite  Adamantanoid
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