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Palladium-catalyzed benzylic direct arylation of benzyl sulfones with aryl halides
Authors:Takashi Niwa  Koichiro Oshima
Affiliation:Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
Abstract:An effective palladium catalyst system for the direct arylation of benzyl sulfones with aryl halides has been developed. The catalytic reaction provides a facile route to diarylmethyl sulfones. The products can be transformed further via desulfonylative functionalization mediated by aluminum compounds.
Keywords:Direct arylation   Palladium catalysis   Diarylmethyl sulfone
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