Palladium-catalyzed benzylic direct arylation of benzyl sulfones with aryl halides |
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Authors: | Takashi Niwa Koichiro Oshima |
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Affiliation: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan |
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Abstract: | An effective palladium catalyst system for the direct arylation of benzyl sulfones with aryl halides has been developed. The catalytic reaction provides a facile route to diarylmethyl sulfones. The products can be transformed further via desulfonylative functionalization mediated by aluminum compounds. |
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Keywords: | Direct arylation Palladium catalysis Diarylmethyl sulfone |
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