Calorimetric determination of the heats of formation of lanthanide monosulfate complexes in D2O1期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Calorimetric determination of the heats of formation of lanthanide monosulfate complexes in D2O1

Authors:	Michael M. Farrow Neil Purdie Wesley D. White

Affiliation:	(1) Department of Chemistry, Oklahoma State University, 74074 Stillwater, Oklahoma

Abstract:	Heats of formation of rate-earth monosulfate complexes have been measured calorimetrically for the ions La³⁺, Sm³⁺, Tb³⁺, and Er³⁺, in D₂O and H₂O solvents. Within the limits of experimental error there is no evidence for a solvent isotope effect on the heat and entropy changes of these complexation reactions.This paper was abstracted from W.D.W.'s Ph.D. dissertation, May 1973.

Keywords:	Calorimetry lanthanide sulfates solvent isotope effect heavy water
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