Precipitation-driven self-sorting of imines |
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Authors: | Lirag Rio Carlo Osowska Karolina Miljanić Ognjen Š |
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Affiliation: | University of Houston, Department of Chemistry, 136 Fleming Building, Houston, TX 77204-5003, USA. |
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Abstract: | ![]() Judicious choice of precipitation conditions can lead to self-sorting of equilibrating mixtures of aromatic aldehydes and substituted anilines into a handful of imine products. The selectivity of this process is caused by the solubility differences among possible imines in the EtOH-H(2)O solvent mixtures used in precipitation. |
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