Binuclear iron(III) acetates |
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Authors: | Sham K. Vasisht Ramesh C. Narula |
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Affiliation: | (1) Department of Chemistry, Panjab University, 160014 Chandigarh, India |
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Abstract: | Summary The binuclear iron(III) compound, Fe2Cl(OH)2(MeCO2)3 2 AcOH combines with pyridine, -picoline and 2,2-bipyridyl (B) to form Fe2Cl(OH)2(AcO)3·B adducts. The secondary bases, pyrrolidine and diethylamine (RNH), on the other hand, combine with the complete elimination of chlorine to form, Fe2(NR)(OH)2(AcO)3. These products have been characterised by molecular weight, i.r. spectra, magnetic susceptibility and Mössbauer measurements. |
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