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| A Novel （4,6）-Connected Net Based on Dysprosium Benzenedicarboxylate, [Dy（OAc）（BDC）]n | |
| 引用本文： | ZHANG Lei LI Zhao-Ji QIN Ye-Yan CHENG Jian-Kai YAO Yuan-Gen. A Novel （4,6）-Connected Net Based on Dysprosium Benzenedicarboxylate, [Dy（OAc）（BDC）]n[J]. 结构化学, 2008, 27(8): 915-918 |
| 作者姓名： | ZHANG Lei LI Zhao-Ji QIN Ye-Yan CHENG Jian-Kai YAO Yuan-Gen |
| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
| 基金项目： | 国家重点基础研究发展计划(973计划)，中国科学院基金，国家自然科学基金，福建省科研项目，Fund of Fujian Key Laboratory of Nanomaterials，中国科学院知识创新工程项目 |
| 摘 要： | A new lanthanide coordination polymer, [Dy（OAc）（BDC）]n 1 （OAc = acetate, BDC = 1,4-benzenediacarboxylate）, has been synthesized under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that complex 1 has infinite zigzag Dy-OAc chains, which are further connected by BDC to form a 3D metal-organic framework. According to topology analysis, this framework can be characterized as （4,6）-connected （3.4.54）（32.4.56.66） net that has never been reported before. Crystal structure for 1： space group Pbca, a = 13.314（3）, b = 8.0269（18）, c = 20.275（5）A, V= 2166.8（9）A3, C10H7O6Dy, Mr = 385.66, Z= 8, Dc = 2.364 g/cm^3, μ= 6.910 mm^-1, F（000） = 1448, the final R = 0.0181 and wR = 0.0520. |
| 关 键 词： | 镝聚合体 1,4-苯羧酸酯 醋酸酯 拓扑学 |
A Novel (4,6)-Connected Net Based on Dysprosium Benzenedicarboxylate, [Dy(OAc)(BDC)]n |
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| ZHANG Lei,LI Zhao-Ji,QIN Ye-Yan,CHENG Jian-Kai,YAO Yuan-Gen. A Novel (4,6)-Connected Net Based on Dysprosium Benzenedicarboxylate, [Dy(OAc)(BDC)]n[J]. Chinese Journal of Structural Chemistry, 2008, 27(8): 915-918 | |
| Authors: | ZHANG Lei LI Zhao-Ji QIN Ye-Yan CHENG Jian-Kai YAO Yuan-Gen |
| Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
| Abstract: | A new lanthanide coordination polymer, [Dy(OAc)(BDC)]n 1 (OAc= acetate, BDC = 1,4-benzenediacarboxylate), has been synthesized under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that complex 1 has infinite zigzag Dy-OAc chains, which are further connected by BDC to form a 3D metal-organic framework. According to topology analysis, this framework can be characterized as (4,6)-connected (3.4.54)(32.4.56.66) net that has never been reported before. Crystal structure for 1: space group Pbca, a = 13.314(3), b = 8.0269(18), c = 20.275(5) A, V = 2166.8(9) A3, C10H7O6Dy, Mr= 385.66, Z = 8, Dc = 2.364 g/cm3, μ = 6.910 mm-1, F(000) = 1448, the final R = 0.0181 and wR = 0.0520. |
| Keywords: | dysprosium polymer 1 4-benzenediaearboxylate acetate topology |
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