| CS_2在Cu－S键中插入产物（Ph_3P）_2Cu（S_2CSR）与溶剂反应的 |
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| 引用本文： | 金祥林,汤卡罗,夏天兵,唐有祺.CS_2在Cu－S键中插入产物（Ph_3P）_2Cu（S_2CSR）与溶剂反应的[J].结构化学,1995(3). |
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| 作者姓名： | 金祥林 汤卡罗 夏天兵 唐有祺 |
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| 作者单位： | 北京大学物理化学研究所 |
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| 摘 要： | ＣＳ_２在Ｃｕ－Ｓ键中插入产物（Ｐｈ_３Ｐ）_２Ｃｕ（Ｓ_２ＣＳＰｈ）与ＣＨ_２Ｃｌ_２－Ｃ_２Ｈ_５ＯＨ混合溶剂反应，获得单核铜配合物（Ｐｈ_３Ｐ）_２Ｃｕ（Ｓ_２ＣＯＯＣ_２Ｈ_５）和双核铜配合物（Ｐｈ_３Ｐ）_３Ｃｕ_２Ｃｌ_２等化合物晶体，用Ｘ－射线单晶衍射法测定前者的晶体结构。晶体的化学式为Ｃ_（３９）Ｈ_（３５）ＣｕＯＰ_２Ｓ_２，分子量为７０９．３，空间群Ｐ２１／ｎ，ａ＝９．３２９（６），ｂ＝１８．６６４（１１），ｃ＝２０，３４１（１３），β＝９５．５９（５）°，Ｖ＝３５２５（４）~３，Ｄ_ｃ＝１．３３７ｇ／ｃｍ~３，Ｚ＝４，Ｆ（０００）＝１４９２，μ＝０．８５２ｍｍ~（－１），Ｒ＝０．０４５。
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| 关 键 词： | CS_2，插入反应，铜配合物，二硫代碳酸酯，晶体结构，活性分子片，自组装 |
Study on the Reaction of Mononuclear Copper Complexes Formed by Insertion of CS_2 into Cu-S Bonds with Various Solvents ──Ⅱ. Formation and Crystal Structure of (Ph_3P)_2Cu(S_2COC_2H_5 ) |
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| Jin Xiang-Lin,Tang Ka-Lou,Xia Tian-Bing,Tang You-Qi.Study on the Reaction of Mononuclear Copper Complexes Formed by Insertion of CS_2 into Cu-S Bonds with Various Solvents ──Ⅱ. Formation and Crystal Structure of (Ph_3P)_2Cu(S_2COC_2H_5 )[J].Chinese Journal of Structural Chemistry,1995(3). |
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| Authors: | Jin Xiang-Lin Tang Ka-Lou Xia Tian-Bing Tang You-Qi |
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| Abstract: | Mononuclear copper complexes with structure of (Ph_3P)_2Cu (S_2CSR) formed by insertion of CS_2 into Cu-S bonds can react with various solvents undergoing some nucleophilic reactions.The title compound was obtained from the reaction of starting material (Ph_3P)_2 Cu (S_2CSPh)with CH_2Cl_2-C_2H_5OH mixed solvent and then self-assembly in the solution.The crystal belongs to the space group P2_1/n ,a= 9. 329(6),b= 18.664(11),c= 20.341 (13)A,β= 95. 59(5)°,V =3525(4) A 3.D_c =1. 337 g/cm￣3.Z= 4. The final R is 0. 045 for 3150 independent reflecrions.The complex contains a dithiocarbonate ligand. |
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| Keywords: | insertion of CS_2 copper complex crystal structure dithiocarbonate activated fragment self-assembly |
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