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The first total synthesis of ligudentatin A |
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| Authors: | Chen Xi Zhang Fu Qiang Bi Yu Lin Li |
| Institution: | State Key Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000, China |
| Abstract: | Ligudentatin A 1,a new phenolic norsesquiterpenes,was first synthesized starting from ( )-periUaldehyde 3 through five steps,successively,in an overall yield of 20.8%.The key steps were the Diels-Alder reaction and aromatization of enone to phenol. |
| Keywords: | Ligudentatin A ( )-Perillaldehyde Diels-Alder reaction Aromatization |
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