Reactions of theortho-metallated rhodium(I) complex of the formula Rh[P(OC6H4)(OPh)2][P(OPh)3]3 with HX molecules期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Reactions of theortho-metallated rhodium(I) complex of the formula Rh[P(OC6H4)(OPh)2][P(OPh)3]3 with HX molecules

Authors:	Anna M Trzeciak Józef J Zio?kowski

Institution:	(1) Institute of Chemistry, University of Wrocaw, 50-383 Wrocaw, Poland

Abstract:	Summary Theortho-metallated complex RhP₃Pt] P=P(OPh)₃, P=P(OC₆H₄)(OPh)₂] was obtained in the reaction of RhP₄]ClO₄ with KOH. It reacts easily with proton donors HX (X=ClO₄, F, Cl, SCN, or acetylacetonate) to produce complexes RhP₃X] when X is a strong donor. If X is a weaker donor (X=ClO₄ or F), pentacoordinate compounds of the type PhP₄X] are formed. RhP₃P] reacts with acetylacetone (Hacac) to produce Rh(acac)P₂].

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