| 多齿配体2,5-二羟基-1,4-苯醌缩氨基脲(C6H4O3NNHCONH2.CHON(CH3)2)的合成及晶体结构 |
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| 引用本文： | 孙燕琼,杨融生,张汉辉,孙瑞卿,杨齐愉. 多齿配体2,5-二羟基-1,4-苯醌缩氨基脲(C6H4O3NNHCONH2.CHON(CH3)2)的合成及晶体结构[J]. 结构化学, 2002, 21(1): 83-86 |
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| 作者姓名： | 孙燕琼 杨融生 张汉辉 孙瑞卿 杨齐愉 |
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| 作者单位： | 福州大学化学系,福州,350002;中科院福建物质结构研究所,结构化学国家重点实验室,材料化学与物理研究所,福州,350002;福州大学化学系,福州,350002 |
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| 基金项目： | 结构化学国家重点实验室资助项目 |
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| 摘 要： | 报道了含1个溶剂DMF的多齿配体2,5-二羟基-1,4-苯醌缩氨基脲的合成和晶体结构。该化合物(C10N4O5H14)属正交晶系,其空间群为P212121 a=13.221(6),b=17.709(5),c=5.347(4)?, V=1252.0(1)3,Z=4,F(000)=568, Dx=1.434g/cm3,Mr=270.25, m (MoKα)= 1.16 cm-1, 结构由直接法解出,全矩阵最小二乘法修正,最终的偏离因子R=0.0319,wR=0.0748。结构测定表明溶剂DMF分子和2,5-二羟基-1,4苯醌缩氨基脲间形成很强的氢键,后者可看作是两条共轭链的偶合物。
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| 关 键 词： | 2 5-二羟基-1 4-苯醌缩氨基脲 晶体结构 氢键 偶合物 |
Study on the synthesis and Crystal Structure of Multidentate Ligand 4-(2,5-Dihydroxy-1,4-benzoquinonyl)-semicarbazide |
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| Abstract: | The synthesis and crystal structure of multidentate ligand 4-(2,5-dihydroxy-1,4-benzoquinonyl)- semicarbazide are reported in this paper. The title compound is orthorhombic with space group P212121, a=13.221(6),b=17.709(5),c=5.347(4)? V=1252.0(1)3,Z=4,F(000)=568, Dx=1.434g/cm3,Mr=270.25, m (Mo-Kα)= 1.16 cm-1. The crystal structure was determined by direct methods, and refined by full-matrix least-squares method for the final R=0.0319 and wR=0.0748.There are two intermolecular hydrogen bonds between the 4-(2,5-dihydroxy-1,4-benzoquinonyl)-semicarbazide and DMF. 4-(2,5-dihydroxy-1,4-benzoquin onyl)- semicarbazide is a coupling compound of two conjugate chains. |
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| Keywords: | dihydroxy-1 4-benzoquinonyl)-semicarbazide crystal structure hydrogen band coupling compound |
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