| A New Synthetic Route to 12-Oxo-1, 15-pentadecanlactam |
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| 引用本文： | JiaXingHUANG XiaoMeiLIANG DaoQuanWANG. A New Synthetic Route to 12-Oxo-1, 15-pentadecanlactam[J]. 中国化学快报, 2004, 15(2): 169-170 |
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| 作者姓名： | JiaXingHUANG XiaoMeiLIANG DaoQuanWANG |
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| 作者单位： | KeyLaboratoryofPesticideChemistryandApplicationTechnology,DepartmentofAppliedChemistry,ChinaAgriculturalUniversity,Beijing100094 |
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| 摘 要： | 12-Oxo-1,15-pentadecanlactam 7 was synthesized from cyclododecanone with a totalyield of 36% in a seven-step reaction. The azide 5 to 12-nitro-1,15-pentadecanlactam 6 is the key step featured by direct ring expansion.
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| 关 键 词： | 合成 位置选择性 12-氧-1，15-十五内酰胺 扩环作用 |
A New Synthetic Route to 12-Oxo-1, 15-pentadecanlactam |
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| Jia Xing HUANG,Xiao Mei LIANG,Dao Quan WANG Key Laboratory of Pesticide Chemistry and Application Technology. A New Synthetic Route to 12-Oxo-1, 15-pentadecanlactam[J]. Chinese Chemical Letters, 2004, 15(2): 169-170 |
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| Authors: | Jia Xing HUANG Xiao Mei LIANG Dao Quan WANG Key Laboratory of Pesticide Chemistry Application Technology |
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| Affiliation: | Jia Xing HUANG,Xiao Mei LIANG,Dao Quan WANG* Key Laboratory of Pesticide Chemistry and Application Technology,Department of Applied Chemistry,China Agricultural University,Beijing 100094 |
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| Abstract: | Oxo-1, 15-pentadecanlactam 7 was synthesized from cyclododecanone with a total yield of 36% in a seven-step reaction. The azide 5 to 12-nitro-1, 15-pentadecanlactam 6 is the key step featured by direct ring expansion. |
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| Keywords: | Macrolactam synthesis ring enlargement. |
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