Intramolecular hydrogen bonding in some acyclic alcohols |
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| Authors: | A B Foster A H Haines and M Stacey |
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| Institution: | Chemistry Department, The University, Birmingham. U.K. |
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| Abstract: | The extent of intramolecular hydrogen bonding, occurring in dilute CCl4 solutions, of members of the series (n = 2–5) HO.(CH2)n.OH and MeO.(CH2)n.OH has been determined. The results permit the interpretation of the patterns of hydrogen bonding in the three monomethyl ethers of butane-1,2,4-triol and in 1,4-dimethoxybutan-2-ol. In these compounds, where hydrogen bonding allows the formation of rings of different sizes the sequence of preference 5> 6> 7 was observed. |
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