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Vibrational spectra of Zn(II) complexes of the amino acids with hydrophobic residues
Authors:Claudia C. Wagner  Enrique J. Baran  
Affiliation:aDepartamento de Ingeniería Química, Facultad de Ingeniería, Universidad Nacional del Centro de la Provincia de Buenos Aires, 7400 Olavarría, Argentina;bCentro de Química Inorgánica (CEQUINOR, CONICET/UNLP), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C. Correo 962, 1900 La Plata, Argentina
Abstract:The infrared and Raman spectra of the bis-chelated Zn(II) complexes of the amino acids glycine, alanine, valine, leucine, isoleucine and phenylalanine were recorded and analyzed in relation to its structural peculiarities. Some comparisons between the recorded spectra are also presented and the characteristics of the carboxylate motions as well as those of the metal-to-ligand vibrations are discussed in detail.
Keywords:Zinc(II)   Amino acid complexes   Infrared spectra   Raman spectra
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