Antioxidants and stabilizers: Part IC—Hydroperoxide deactivation by aliphatic sulfides. A model study |
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Authors: | I Kúdelka PK Misro J Pospí?il H Korbanka T Riedel G Pfahler |
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Institution: | Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06 Prague 6, Czechoslovakia;Hoechst AG Werk Gersthofen, 8900 Augsburg 1, Federal Republic of Germany |
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Abstract: | The hydroperoxide decomposing efficiencies of dioctadecylsulfide (I), dioctadecyldisulfide (IV) and dioctadecyl 3,3-thio-dipropionate (VII) have been compared at 75°C and 85°C. The formation of oxidation products from (I) and (IV) has been checked. Experimental evidence is given of the important rôle of the activation of the molecule of (IV) by the presence of two sulfidic sulfur atoms compared with the activation of the sulfur atom in (VII) by the alkoxycarbonyl group in the beta position. The explanation of the high efficiency of disulfide has been based on the formation of thiosulfinate—the key intermediate for the generation of peroxidolytic species—in the first reaction step. |
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