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Synthesis of Sybstituted Isoxazoles and Pyrazoles Based on 1-Aryl-3,4,4-trichloro-3-buten-1-ones
Authors:S. K. Petkevich  V. I. Potkin  R.V. Kaberdin
Affiliation:(1) Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, 220072, Belarus
Abstract:3-Aryl-5-methylenehydroxyiminoisoxazoles were synthesized by reaction of 1-aryl-3,4,4-trichloro-3-buten-1-ones with hydroxylamine. Reactions of ketones with hydrazine provided pyrazole structures; therewith two pyrazole molecules underwent ldquocouplingrdquo affording 3-arylpyrazole-5-carbaldehyde azines.
Keywords:
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