How long a C–C bond can be? An example of extraordinary long C–C single bond in 1,2-diarylamino-o-carborane |
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作者姓名: | Yile Wu Jie Zhang Zuowei Xie |
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作者单位: | Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Hong Kong, China |
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基金项目: | This work was supported by a grant from the Research Grants Council of the Hong Kong Special Administration Region (No. 14305918). |
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摘 要: | The longest C-C single bond of 1.990(4) Å known thus far is observed in the single crystal X-ray structure of 1,2-(NHMes)2-o-carborane (Mes = 2,4,6-trimethylphenyl), which is readily synthesized via a one-pot process.
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收稿时间: | 15 February 2019 |
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