Thermochemistry of decomposition of manganese(II) oxalate dihydrate |
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| Authors: | Michael Ewart Brown David Dollimore Andrew K. Galwey |
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| Affiliation: | Chemistry Department, Rhodes University, Grahamstown, 6140 South Africa;Department of Chemistry, University of Salford, Salford M5 4WT England;Department of Chemistry. Queen''s University, Belfast BT9 5AG Northern Ireland |
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| Abstract: | Differential scanning calorimetry (DSC) has been used to determine the enthalpy of dehydration of manganese(II) oxalate dihydrate and the enthalpies of decomposition in nitrogen and in oxygen of the anhydrous oxalate. The thermodynamic data have been related to the activation energies reported in kinetic studies and to the mechanisms proposed for the thermal decomposition and oxidation processes. |
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