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13C-NMR. Spectroscopy of naturally occurring substances. XXXII. Vincaleucoblastine and related alkaloids.
Authors:E Wenkert  E W Hagaman  B Lal  G E Gutowski  A S Katner  J C Miller  N Neuss
Abstract:
The total assignment of the 13C-shifts of the complex Vinica rosea L. alkaloids vincaleucoblastine, leurosidine and leurosine and of a synthetic isomer of the latter is presented. The structure of leurosidine is corrected and a tentative structure for the acid-catalyzed product of isomerization of leurosine is proposed.
Keywords:
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