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Microwave‐Assisted Dibromoolefination of Aromatic and Heteroaromatic Aldehydes and Ketones
Authors:Djawed Nauroozi  Clemens Bruhn  Sven Fürmeier  Jörn‐Uwe Holzhauer  Rüdiger Faust
Affiliation:Institute for Chemistry and CINSaT—Center for Interdisciplinary Nanostructure Science and Technology, University of Kassel, Kassel, Germany
Abstract:
Microwave (MW) irradiation was successfully employed to convert aromatic and heteroaromatic aldehydes and ketones efficiently to the corresponding dibromoolefins. Exemplified by the successful dibromoolefination of traditionally inert pyridyl‐flanked carbonyls, MW activation significantly broadens the scope of this valuable transformation, although some limitations especially with electron‐rich aromatic ketone derivatives remain.
Keywords:
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