Crystal structure and EPR spectra of (Bu4N)2[V(dmit)3] |
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| Authors: | Ya. S. Fomenko A. L. Gushchin V. A. Nadolinny P. A. Abramov M. N. Sokolov |
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| Affiliation: | 1.Nikolaev Institute of Inorganic Chemistry, Siberian Branch,Russian Academy of Sciences,Novosibirsk,Russia;2.Novosibirsk National Research State University,Novosibirsk,Russia |
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| Abstract: | The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S5 2–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined. |
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