Lewis acid-activated oxidation of alcohols by permanganate |
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| Authors: | Du Hongxia Lo Po-Kam Hu Zongmin Liang Haojun Lau Kai-Chung Wang Yi-Ning Lam William W Y Lau Tai-Chu |
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| Affiliation: | CAS Key Laboratory of Soft Matter Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China. |
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| Abstract: | ![]()
The oxidation of alcohols by KMnO(4) is greatly accelerated by various Lewis acids. Notably the rate is increased by 4 orders of magnitude in the presence of Ca(2+). The mechanisms of the oxidation of CH(3)OH and PhCH(OH)CH(3) by MnO(4)(-) and BF(3)·MnO(4)(-) have also been studied computationally by the DFT method. |
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