Si(SiMe3)3]3Ge9M(CO)3(-) (M=Cr, Mo, W): coordination chemistry with metalloid clusters

Very recently it was shown that the metalloid cluster compound {Ge(9)Si(SiMe(3))(3)](3)}(-)1 can be used for subsequent reactions as the shielding of the cluster core is rather incomplete. So the reaction of 1 with Cr(CO)(3)(CH(3)CN)(3) leads to a cluster enlargement where the chromium atom is incorporated into the cluster core. Here further applications of 1 as a flexible ligand in coordination chemistry are presented where the reaction of 1 with Mo(CO)(3)(EtCN)(3) and W(CO)(3)(CH(3)CN)(3) leads to (CO)(3)MoGe(9)R(3)](-)4 and (CO)(3)WGe(9)R(3)](-)5 respectively (R = Si(SiMe(3))(3)), showing that 1 can indeed be used as a flexible ligand in coordination chemistry. Structural and electronic properties of the Ge(9)M clusters 4 and 5 are discussed as well as mechanistic aspects of their formation.