Mathematical modeling of a slurry reactor for DME direct synthesis from syngas |
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Authors: | Sadegh Papari Mohammad Kazemeini Moslem Fattahi |
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Institution: | Department of Chemical and Petroleum Engineering,Sharif University of Technology,Azadi Avenue,P.O.Box 11365-9465,Tehran,Iran |
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Abstract: | In this paper,an axial dispersion mathematical model is developed to simulate a three-phase slurry bubble column reactor for direct synthesis of dimethyl ether(DME) from syngas.This large-scale reactor is modeled using mass and energy balances,catalyst sedimentation andsingle-bubble as well as two-bubbles class flow hydrodynamics.A comparison between the two hydrodynamic models through pilot plantexperimental data from the literature shows that heterogeneous two-bubbles flow model is in better agreement with the experimental data thanhomogeneous single-bubble gas flow model.Also,by investigating the heterogeneous gas flow and axial dispersion model for small bubblesas well as the large bubbles and slurry(i.e.including paraffins and the catalyst) phase,the temperature profile along the reactor is obtained.Acomparison between isothermal and non-isothermal reactors reveals no obvious performance difference between them.The optimum values ofreactor diameter and height were obtained at 7 m and 50 m,respectively.The effects of operating variables on the axial catalyst distribution,DME productivity and CO conversion are also investigated in this research. |
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Keywords: | modeling large-scale slurry bubble column optimization dimethyl ether synthesis single-bubble class two-bubbles class isotherm andnon-isotherm |
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