Synthesis,Structures, and Luminescent Properties of two 3, 5‐Dimethyl‐1‐H‐1, 2,4‐triazole‐Based Zinc Metal‐Organic Frameworks with Aromatic Carboxylate as Coligand |
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| Authors: | Yao Huang Long‐Jiang Liu Ming‐Shan Zhou Xiao‐Jun Zhou Chao Zhu Fei‐E Fu Yong‐Ming Zhang |
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| Institution: | Key Laboratory Cultivation Base for Special Energy Engineering, College of Yunnan, School of Chemical Engineering, Yunnan Open University, Kunming, 650500, P. R. China |
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| Abstract: | Two metal‐organic frameworks, Zn(dmtrz)(btrc)1/3]n ( 1 ) and Zn2(dmtrz)2(btec)(H2O)2]n ( 2 ) (dmtrz = 3, 5‐dimethyl‐1‐H‐1, 2,4‐triazole, btrc = 1, 3,5‐benzenetricarboxylate, btec = 1, 2,4, 5‐benzenetetracarboxylate), were synthesized by hydrothermal reaction. The crystal structure analysis reveals that compound 1 is a dense 3D framework with Schläfli symbols of {43}2{46 · 66 · 83}3, which is a loh1 structure. Compound 2 is a 2D network. In addition, the photoluminescence of two compounds were studied in solid state at room temperature, together with their thermal analysis. |
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| Keywords: | Triazole Aromatic acid Metal‐organic frameworks Topology Luminescence |
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