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Spatial and temporal variation of H and O isotopic compositions of the Xijiang River system,Southwest China
Authors:Guilin Han  Pin Lv  Yang Tang  Zhaoliang Song
Institution:1. School of Scientific Research, China University of Geosciences, Beijing, People’s Republic of China;2. The State Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, People’s Republic of China;3. Institute of the Surface-Earth System Science Research, Tianjin University, Tianjin, People’s Republic of China
Abstract:Ratios of stable isotopes of hydrogen and oxygen (2H/1H and 18O/16O) in river waters were measured to investigate the hydrological pathway of the Xijiang River, Southwest China. The δ2H and δ18O values of river waters exhibit significant spatial and temporal variations and the isotopic compositions vary with elevation, temperature and precipitation of the recharge area. Spatially, δ18O values of river waters from high mountain areas are lower than those from the lower reaches of the Xijiang River due to lower temperature and higher elevation for the recharge area. However, both 2H and 18O are enriched differently in river waters from the middle reaches during the high flow season, depending on the season and degree of anthropogenic disturbances (e.g. water impoundments). In contrast, deuterium excess (d-excess) values of waters from the middle reaches are substantially lower than those from the upper and lower reaches, suggesting that river waters may be resided in the reservoir and evaporation increases in the middle reaches of the Xijiang River.
Keywords:Deuterium excess  hydrogen-2  isotope hydrology  oxygen-18  river water  Southwest China  Xijiang River
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