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| SYNTHESIS AND CATALYTIC PROPERTY OF POLYSTYRENE SUPPORTED GLUTAMIC ACID SCHIFF BASE COMPLEX OF Mn（ Ⅱ ） IN AEROBIC OXIDATION OF CYCLOHEXENE | |
| 引用本文： | CHEN Songtao,;ZHAO Ganqing,;LU Xiaoqing,;XIE Jimin. SYNTHESIS AND CATALYTIC PROPERTY OF POLYSTYRENE SUPPORTED GLUTAMIC ACID SCHIFF BASE COMPLEX OF Mn（ Ⅱ ） IN AEROBIC OXIDATION OF CYCLOHEXENE[J]. 反应性高分子(英文版), 2007, 16(1): 112-118 |
| 作者姓名： | CHEN Songtao, ZHAO Ganqing, LU Xiaoqing, XIE Jimin |
| 作者单位： | CHEN Songtao（College of Chemistry and Chemical Engineering, Jiangsu University Zhenjiang 212013, China;Department of Chemical Engineering, Pingdingshan Institute of Technology Pingdingshan 467001, China） ;ZHAO Ganqing（College of Chemistry and Chemical Engineering, Jiangsu University Zhenjiang 212013, China） ;LU Xiaoqing（College of Chemistry and Chemical Engineering, Jiangsu University Zhenjiang 212013, China） ;XIE Jimin（College of Chemistry and Chemical Engineering, Jiangsu University Zhenjiang 212013, China） ; |
| 摘 要： | The polystyrene supported glutamic acid Schiff base complex of Mn （ Ⅱ ） （PS-Sal-Glue-Mn） was prepared with chloromethylated styrene polymer beads, 2,4-dihydroxybenzaldehyde, L-glutamic acid and manganese （ Ⅱ ） acetate tetrahyrate. The polymeric ligand and the complex were characterized by FT-IR, small area X-ray photoelectron spectroscopy （XPS） and 1CP-AES. In the presence of the manganese complex, cyclohexene （1） was effectively oxidized by molecular oxygen without reductant. The major products of the reaction were 2-cyclohexen-l-ol （2）, 2-cyclohexen-l-one （3） and 2-cyclohexen-1- hydroperoxide （4）, which was different with typical oxidation of cyclohexene. The influence of reaction temperature and additive for oxidation had been studied. The selectivity of 2-cyclohexen-1-hydroperoxide varied with reaction time and different additives. The mechanism of cyclohexene oxidation had also been discussed. |
| 关 键 词： | 芳香烃 氧化反应 化学 聚苯乙烯 |
SYNTHESIS AND CATALYTIC PROPERTY OF POLYSTYRENE SUPPORTED GLUTAMIC ACID SCHIFF BASE COMPLEX OF Mn（ Ⅱ ） IN AEROBIC OXIDATION OF CYCLOHEXENE |
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| CHEN Songtao ZHAO Ganqing LU Xiaoqing XIE Jimin. SYNTHESIS AND CATALYTIC PROPERTY OF POLYSTYRENE SUPPORTED GLUTAMIC ACID SCHIFF BASE COMPLEX OF Mn（ Ⅱ ） IN AEROBIC OXIDATION OF CYCLOHEXENE[J]. Chinese Journal of Reactive Polymers, 2007, 16(1): 112-118 | |
| Authors: | CHEN Songtao ZHAO Ganqing LU Xiaoqing XIE Jimin |
| Affiliation: | [1]College of Chemistry and Chemical Engineering, Jiangsu University Zhenjiang 212013, China [2]Department of Chemical Engineering, Pingdingshan Institute of Technology Pingdingshan 467001, China |
| Abstract: | Aerobic oxidation Polystyrene supported manganese complex Cyclohexene Glutamic acid. |
| Keywords: | Aerobic oxidation Polystyrene supported manganese complex Cyclohexene Glutamic acid. |
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