PMR study of Cd(II) complexes with 2,2′-bipyridine |
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| Authors: | B. Je owska-Trzebiatowska, G. Formicka-Koz&#x owska, H. Koz&#x owski, L. Latos-Gra y&#x ski,T. Kowalik |
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| Affiliation: | B. Jeżowska-Trzebiatowska, G. Formicka-Kozłowska, H. Kozłowski, L. Latos-Grażyński,T. Kowalik |
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| Abstract: | The NMR method has been used to study the structure of the complexes [Cd(bipy)]SO4.4H2O, [Cd(bipy)](NO3)2.2H2O, [Cd(bipy)2](NO3)2.H2O and [Cd(bipy)3](NO3)2.7H2O. The influence of the central ion and of diamagnetic currents of the rings in these complexes on the PMR spectrum has been investigated. In the complexes [Cd(bipy)](NO3)2.2H2O and [Cd(bipy)]SO4.4H2O two kinds of hydration isomers, with different PMR spectra, have been obtained. |
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