Multiblock copolymer synthesis via controlled radical polymerization in aqueous dispersions. Part 1: Synthesis of S-tert-alkyl-N,N-alkoxycarbonylalkyldithiocarbamates |
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| Authors: | Raf Bussels |
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| Institution: | Laboratory of Polymer Chemistry, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The Netherlands |
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| Abstract: | In a novel two- or three-step synthetic route, S-(1,4-phenylenebis(propane-2,2-diyl)) bis(N-methyldithiocarbamate) is reacted at low temperature with various alkyl chloroformates to form various S-tert-alkyl-N,N-alkoxycarbonylmethyl-dithiocarbamate RAFT agents. Also an alternative and novel synthetic route towards S-(1,4-phenylenebis(propane-2,2-diyl)) bis(N-methyldithiocarbamate), is proposed. |
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| Keywords: | Block copolymer synthesis Alkyl chloroformates Dithiocarbamates Living radical polymerization |
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