Syntheses and Structures of Zinc Bis(phosphinimino)methanide Complexes |
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| Authors: | Melike Bayram Sebastian Gondzik Dieter Bläser Christoph Wölper Stephan Schulz |
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| Institution: | Inorganic Chemistry, University of Duisburg‐Essen, Universit?tsstr. 5–7, S07 S03 C30, 45117 Essen, Germany |
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| Abstract: | Reactions of bis(phosphinimino)methanes H2C(PPh2NR)2 R = SiMe3 (L1H), Ph (L2H), 2,6‐iPr2‐C6H3 (DIPP) (L3H)] with ZnR2 (R = Me, Et) yielded the corresponding bis(phosphinimino)methanide zinc complexes LZnMe L2 ( 1 ), L3 ( 2 )] and LZnEt L1 ( 3 ), L2 ( 4 ), and L3 ( 5 )]. Complexes 1 – 5 were characterized by heteronuclear NMR (1H, 13C, 31P) and IR spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction. |
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| Keywords: | Bis(phosphinimino)methanide Zinc Single crystal structure Heteroleptic complex |
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