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Reactions of Cinnoline, Cinnoline N-Oxides, and Their Chloro Derivatives with Alkylamines: the First Case of Nucleophilic Substitution of Hydrogen in the Cinnoline Series |
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| Authors: | N. A. Buluchevskaya A. V. Gulevskaya A. F. Pozharskii |
| Affiliation: | (1) Rostov State University, Rostov-on-Don, 344090, Russia |
| Abstract: | In contrast to cinnoline and cinnoline N(1)-oxide, cinnoline N(2)-oxide reacts with primary and secondary amines on prolonged heating or in the presence of oxidants to give 3-alkylaminocinnolines. |
| Keywords: | 3-alkylaminocinnolines 4-alkylaminocinnolines 4-chlorocinnoline N(1)-oxide 4-chlorocinnoline N(2)-oxide cinnoline cinnoline N(1)-oxide cinnoline N(2)-oxide aminodehalogenation nucleophilic substitution of hydrogen oxidative amination |
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