A field-desorption study of thermal stability in potassium pentacyanocobaltates(III) |
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| Authors: | G A Kozlov V A Nazarenko G N Mel'nichenko V V Zhilinskaya |
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| Institution: | (1) L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev |
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| Abstract: | Field desorption has been applied to research the thermal stability of the compounds KnCo(CN)5X], where X=SO3
2–, CN–, NO2
–, NO–, Cl–, Br–, I–, and H2O. A likely mechanism is proposed for the thermal decomposition. There is a correlation between the tetragonal-distortion parameters and the temperature of onset of destruction for the Co(CN)5X]n– anion.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 21, No. 1, pp. 111–115, January–February, 1985. |
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