(PCy3)2Cl2RuCHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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(PCy₃)₂Cl₂RuCHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation

Authors:	Belinda T Lee

Institution:	Department of Chemistry, Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467-3860, USA

Abstract:	(PCy₃)₂Cl₂RuCHPh-catalyzed Kharasch additions of trihaloalkanes across olefins provide polyhalogenated adducts, which upon hydrolysis furnish α,β-unsaturated ketones, aldehydes, or γ-hydroxybutenolides. This two-step process represents an overall acylation or carbonylation of an olefin.

Keywords:	Kharasch Metathesis Radical Carbonylation
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